INFIQC   05475
INSTITUTO DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Unidad Ejecutora - UE
artículos
Título:
The Limits of Underpotential Deposition in the Nanoscale.
Autor/es:
O. A. OVIEDO, L. REINAUDI, E. P. M. LEIVA
Revista:
ELECTROCHEMISTRY COMMUNICATIONS
Editorial:
ELSEVIER SCIENCE INC
Referencias:
Lugar: Amsterdam; Año: 2012 vol. 21 p. 14 - 17
ISSN:
1388-2481
Resumen:
A thermodynamic model predicting the disappearance of the underpotential deposition phenomenon in the limit of small nanoparticles is proposed and developed for selected families of geometric bodies. The key parameters are the binding energy of adatoms on the flat foreign substrate and at the edges of the nanoparticle.