INFIQC 05475
INSTITUTO DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Unidad Ejecutora - UE
artículos
Título:
Photostimulated synthesis of 2-(diphenylphosphino)benzoic acid by the SRN1 reaction.
Autor/es:
SILVIA M. BAROLO; SANDRA E MARTÍN*; ROBERTO A. ROSSI*
Revista:
ARKIVOC - ONLINE JOURNAL OF ORGANIC CHEMISTRY
Editorial:
ARKAT USA INC
Referencias:
Lugar: Florida; Año: 2012 p. 98 - 106
ISSN:
1551-7004
Resumen:
2-(Diphenylphosphino)benzoic acid, isolated as the ester, was obtained by the photostimulated reaction of 2-chlorobenzoate ion with Ph2P- ions in good yield in liquid ammonia. The reaction did not occur in the dark; it was inhibited by m-dinitrobenzene and partially inhibited by a radical trap such as TEMPO. The results were consistent with the SRN1 mechanism. No evidences for aromatic nucleophilic substitution (SNAr) or benzyne mechanisms were found.
