Amperometric Response of Hydrogen Peroxide at Carbon Nanotubes Paste Electrodes Modified with an Electrogenerated Poly(Fe(III)-5-amino-phenantroline). Analytical Applications for Glucose Biosensing

MARÍA L. LOZANO; MARCELA C. RODRIGUEZ; PILAR HERRASTI; LAURA GALICIA; GUSTAVO A. RIVAS

ELECTROANALYSIS

WILEY-V C H VERLAG GMBH

Año: 2010 vol. 22 p. 128 - 134

1040-0397

This work reports the catalytic activity of a polymer electrogenerated from Fe(III)-5-amino-1,10-phenantroline solution at a carbon nanotubes paste electrode (CNTPE) towards the oxidation and mainly the reduction of hydrogen peroxide. The important role of carbon nanotubes on the generation of poly(Fe(III)-5-amino-1,10-phenantroline) is demonstrated through the comparison with the behavior of graphite paste electrode (CPE). The polymer electrogenerated at CNTPE largely improves the amperometric detection of hydrogen peroxide at 0.100 V. The analytical application of the resulting electrode is demonstrated in connection with the design of a glucose biosensor based on the deposition of GOx and diluted Nafion on the top of the polymer-modified CNTPE. The quantification of glucose in human serum samples showed a good correlation with the values obtained by the spectrophotometric technique.