INIFTA   05425
INSTITUTO DE INVESTIGACIONES FISICO-QUIMICAS TEORICAS Y APLICADAS
Unidad Ejecutora - UE
artículos
Título:
Fluorescence Quenching by Oxygen: “Debunking” a Classic Rule
Autor/es:
FRANCO M. CABRERIZO; JACOB ARNBJERG; M. PAULA DENOFRIO; ROSA ERRA-BALSELLS; PETER R. OGILBY
Revista:
Chemphyschem
Editorial:
WILEY-VCH Verlag GmbH & Co. KGaA
Referencias:
Lugar: Weinheim; Año: 2010 vol. 11 p. 796 - 798
ISSN:
1439-4235
Resumen:
New clothes for an old player: Oxygen-induced deactivation of a fluorescent state can, in fact, proceed via S1!S0 internal conversion and effectively compete with S1!T1 intersystem crossing (see figure). It has long been considered that only the latter process occurs. An O2-dependent process that does not produce a triplet excited state can have significant photochemical and photobiological consequences. 1!S0 internal conversion and effectively compete with S1!T1 intersystem crossing (see figure). It has long been considered that only the latter process occurs. An O2-dependent process that does not produce a triplet excited state can have significant photochemical and photobiological consequences. 1!T1 intersystem crossing (see figure). It has long been considered that only the latter process occurs. An O2-dependent process that does not produce a triplet excited state can have significant photochemical and photobiological consequences. 2-dependent process that does not produce a triplet excited state can have significant photochemical and photobiological consequences.1!S0 internal conversion and effectively compete with S1!T1 intersystem crossing (see figure). It has long been considered that only the latter process occurs. An O2-dependent process that does not produce a triplet excited state can have significant photochemical and photobiological consequences. 1!T1 intersystem crossing (see figure). It has long been considered that only the latter process occurs. An O2-dependent process that does not produce a triplet excited state can have significant photochemical and photobiological consequences. 2-dependent process that does not produce a triplet excited state can have significant photochemical and photobiological consequences.