INIFTA 05425
INSTITUTO DE INVESTIGACIONES FISICO-QUIMICAS TEORICAS Y APLICADAS
Unidad Ejecutora - UE
artículos
Título:
Metal–organic frameworks meet polymer brushes: enhanced crystalline film growth induced by macromolecular primers
Autor/es:
AZZARONI, OMAR; BINDINI, ELISA; GIUSSI, JUAN M.; TUNINETTI, JIMENA S.; SEGOVIA, GUSTAVO M.; ALLEGRETTO, JUAN A.; RAFTI, MATÍAS
Revista:
Mater. Chem. Front.
Editorial:
RSC
Referencias:
Lugar: londres; Año: 2017
Resumen:
We used poly-(3-sulfopropylmethacrylate) brushes as macromolecular 3D primers to promote heterogeneous nucleation and growth of archetypal ZIF-8 MOF thin films. The enhancement can be understood in terms of a high preconcentration of Zn2+ ions in the polymer brush; this leads to a rapid increase of nucleation sites in the primer.
