INIFTA   05425
INSTITUTO DE INVESTIGACIONES FISICO-QUIMICAS TEORICAS Y APLICADAS
Unidad Ejecutora - UE
artículos
Título:
Excitability in the H2+O2 reaction on a Rh(110) surface induced by high coverages of coadsorbed potassium
Autor/es:
M. RAFTI; R. IMBIHIL
Revista:
JOURNAL OF CHEMICAL PHYSICS
Editorial:
AMER INST PHYSICS
Referencias:
Lugar: New York; Año: 2014 vol. 141 p. 2147071 - 2147075
ISSN:
0021-9606
Resumen:
By means of photoemission electron microscopy as spatially resolving method, the effect of high coverages of coadsorbed potassium (0.16 ≤ θK ≤ 0.21) on the dynamical behavior of the H2 + O2 reaction over a Rh(110) surface was investigated. We observe that the originally bistable system is transformed into an excitable system as evidenced by the formation of target patterns and spiral waves. At K coverages close to saturation (θK ≈ 0.21) mass transport of potassium with pulses is seen.