Manipulation of Molecular Transport into Mesoporous Silica Thin Films by the Infiltration of Polyelectrolytes

ANNETTE BRUNSEN; ALEJANDRA CALVO; FEDERICO J. WILLIAMS; GALO J.A.A. SOLER-ILLIA; OMAR AZZARONI

LANGMUIR

AMER CHEMICAL SOC

Año: 2011 vol. 27 p. 4328 - 4333

0743-7463

The design of hybrid mesoporous materials incorporating polymeric assemblies as versatile functional units has become a very fertile research area offering major opportunities for controlling molecular transport through interfaces. However, the creation of such functional materials depends critically on our ability to assemble polymeric units in a predictable manner within mesopores withdimensions comparable to the size of the macromolecular blocks themselves. In this work, we describe for the first time the manipulation of the molecular transport properties of mesoporous silica thin films by the direct infiltration of polyelectrolytes into the inner environment of the 3D porous framework. The hybrid architectures were built up through the infiltration electrostatic assembly of polyallylamine (PAH) on the mesopore silica walls, and the resulting systems werestudied by a combination of experimental techniques including ellipsoporosimetry, cyclic voltammetry and X-ray photoelectron spectroscopy, among others. Our results show that the infiltrationassembly of PAH alters the intrinsic cation-permselective properties of mesoporoussilica films, rendering them ion-permeable mesochannels and enabling the unrestricted diffusion of cationic and anionic species through the hybrid interfacial architecture. Contrary to what happens during the electrostatic assembly of PAH on planar silica films (quantitative charge reversal), the surface charge of the mesoporous walls is completely neutralized upon assembling the cationicPAH layer (i.e., no charge reversal occurs). We consider this work to have profound implications not only on the molecular design of multifunctional mesoporous thin films but also on understanding the predominant role of nanoconfinement effects in dictating the functional properties of polymer inorganic hybrid nanomaterials.