CINDECA   05422
CENTRO DE INVESTIGACION Y DESARROLLO EN CIENCIAS APLICADAS "DR. JORGE J. RONCO"
Unidad Ejecutora - UE
congresos y reuniones científicas
Título:
Fe/MCM-41 SYLILATED CATALYST. STRUCTURAL CHANGES DETERMINATION
Autor/es:
J.F. BENGOA, N.A. FELLENZ, M.V. CAGNOLI, L.A. CANO, N.G. GALLEGOS, A.M. ALVAREZ, AND S.G. MARCHETTI.
Lugar:
La Plata, Argentina
Reunión:
Simposio; 11th Latin American Conference On Applications Of The Mössbauer Effect; 2008
Resumen:
Sililacin de un sistema de Fe/MCM-41
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Fischer-Tropsch
synthesis (FTS) is a process used to produce a broad distribution of clean" hydrocarbons from syngas using principally Fe catalysts. Although
it has been used industrially for
decades, the main still unresolved problem is to reach a good selectivity toward desirable products. Two main
approaches have been applied to this purpose: controlling the operative variables of the
process (pressure, contact time, reactor selection or temperature) or modifying the
structural properties of the catalysts. The last option is the more promising because the
reaction is kinetically controlled. It is generally accepted that FTS is a
structure-sensitive reaction. A strategy to increase the selectivity is to obtain a catalyst with a narrow
size distribution of active phase crystals which average size is within a determinate
range. If a mesoporous solid like MCM-41 ] would be used as iron support and if it
would be possible to introduce the iron species mainly inside its channels, the small
sizes of the obtained crystals would lead to highly selective catalysts towards the
production of light hydrocarbons (HC),since the growth of chain would be
limited. Nevertheless, these crystals have an activity smaller than the larger ones . For this
reason, the aim of the present work consists in modifying the surface of Fe/MCM-41
catalyst, avoiding the water adsorption, a product of the reaction that leads to active
sites poisoning. This surface modification would compensate the activity decrease due to the
crystal size. With this purpose a sylilation treatment was carried out to eliminate
the supercial hydroxyls, increasing the surface hidrophobicity. Two Fe/MCM-41 systems
were obtained with more than 90% of the iron species located inside the support
channels, leading to a narrow crystal size distribution, accessible to reactive gases. The
samples were characterized by X-ray difraction, atomic absorption spectroscopy, nitrogen
adsorption, Mossbauer spectroscopy and Fourier transformer infrared spectroscopy. Moossbauer spectroscopy allowed us to demonstrate that the catalytic active species were
the same in both catalysts. The only difference between them was the surface hydrophobicity,
that produce a decrease of the \water gas shift reaction in the sylilated catalyst. Besides, this solid is
more active for HC production, with a lower methane yield.