CINDECA   05422
CENTRO DE INVESTIGACION Y DESARROLLO EN CIENCIAS APLICADAS "DR. JORGE J. RONCO"
Unidad Ejecutora - UE
artículos
Título:
Preyssler catalyst: An efficient catalyst for esterification of cinnamic acids with phenols and imidoalcohols
Autor/es:
DIEGO M. RUIZA, , , GUSTAVO P. ROMANELLIA, B, PATRICIA G. VÁZQUEZB AND JUAN C. AUTINOA
Revista:
APPLIED CATALYSIS A-GENERAL
Editorial:
ELSEVIER SCIENCE BV
Referencias:
Lugar: Amsterdam; Año: 2009 vol. 374 p. 110 - 110
ISSN:
0926-860X
Resumen:
<!-- /* Style Definitions */ p.MsoNormal, li.MsoNormal, div.MsoNormal {mso-style-parent:""; margin:0cm; margin-bottom:.0001pt; mso-pagination:widow-orphan; font-size:12.0pt; font-family:"Times New Roman"; mso-fareast-font-family:"Times New Roman";} p {mso-margin-top-alt:auto; margin-right:0cm; mso-margin-bottom-alt:auto; margin-left:0cm; mso-pagination:widow-orphan; font-size:12.0pt; font-family:"Times New Roman"; mso-fareast-font-family:"Times New Roman";} @page Section1 {size:612.0pt 792.0pt; margin:70.85pt 3.0cm 70.85pt 3.0cm; mso-header-margin:36.0pt; mso-footer-margin:36.0pt; mso-paper-source:0;} div.Section1 {page:Section1;} --> In the present work a series of eco-friendly Preyssler solid acids and their salts H14[NaP5W29MoO110] (PW), H14[NaP5W30O110] (PWMo), K12.5Na1.5[NaP5W30O110]·15H2O (PWK), K12.5Na1.5[NaP5W29MoO110]·15H2O (PWMoK) and 10% silica-supported H14[NaP5W29MoO110] (PWSiO2), and H14[NaP5W30O110] (PWMoSiO2) have been used as catalysts for the direct esterification of cinnamic acids with phenols or 2-(N-phthalimidoethanol). Effects of the reaction conditions were studied, including temperature, reaction time, and type and amount of catalyst. These solids were characterized by several techniques, such as diffuse reflectance spectroscopy, Fourier transformed infrared spectroscopy, optical and scanning electron microcopies, and X-ray diffraction, among others. The most adequate catalyst for performing the title reaction was H14[NaP5W30O110] (PWMo). The catalyst was applied for the synthesis of various substituted cinnamates, giving very good yields.
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