CINDECA   05422
CENTRO DE INVESTIGACION Y DESARROLLO EN CIENCIAS APLICADAS "DR. JORGE J. RONCO"
Unidad Ejecutora - UE
artículos
Título:
Co-Rh modified natural zeolites as new catalytic materials to remove propane and naphthalene from emission sources
Autor/es:
M.ELENA CANAFOGLIA; IRMA L. BOTTO; MARCO.A.OCSACHOQUE; M.SILVIA LEGUIZAMÓN APARICIO; ILEANA D. LICK
Revista:
Open Chemistry
Editorial:
DE GRUYTER OPEN
Referencias:
Lugar: Warsaw; Año: 2016 vol. 14 p. 335 - 335
ISSN:
2391-5420
Resumen:
Natural zeolites as a raw material to prepare catalytic precursors for the oxidation reaction of linear and poly-aromatic hydrocarbons are reported in this work. The process consisted in the formation of mono- and bi-metallic species containing Co and Co-Rh on natural zeolite tuffs. The materials are analyzed by different physicochemical techniques and used as catalysts for propane and naphthalene oxidation in emissions sources. Comparatively, Rh-zeolites are the most active catalysts for propane conversion. In this case, the formation of mixed oxides seems to be conditioned by surface properties. It could also be suggested that the Rh incorporation on a non-active phase in bimetallic catalysts impacts the effectiveness of the system. In addition, the NO presence increases the activity of bimetallic materials. Rh-Co zeolite systems markedly influence the naphthalene combustion temperature. Whereas in the absence of a catalyst a conversion rate of 50% and 100% is reached at 430 oC and 485 oC, respectively. It is interesting to observe that for RhCoCli-Mor and RhCoCli catalyst the 100% conversion is reached at 250 oC.
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