CINDECA 05422
CENTRO DE INVESTIGACION Y DESARROLLO EN CIENCIAS APLICADAS "DR. JORGE J. RONCO"
Unidad Ejecutora - UE
artículos
Título:
Asymmetric hydrogenation of 3,4-hexanedione over PtSn catalysts.
Autor/es:
VIRGINIA VETERE; MARÍA B. FARAONI; JULIO C. PODESTÁ; MÓNICA L. CASELLA
Revista:
CATALYSIS LETTERS
Editorial:
SPRINGER
Referencias:
Lugar: Amsterdam; Año: 2010 vol. 138 p. 34 - 39
ISSN:
1011-372X
Resumen:
In this work, some results of the liquid-phase racemic and enantioselective hydrogenation of 3,4-hexanedione are presented. The catalysts employed were platinum-based, supported on SiO2. Monometallic catalysts were modified with organotin precursors either chiral (hexa(-)-menthylditin, Men3SnSnMen3) or achiral (tetrabutyltin, SnBu4), and they were obtained via surface organometallic chemistry on metals techniques. Asymmetric system was selective to 4-hydroxyhexan-3-one, the enantiomeric excess achieved being 17%.
