CEQUINOR   05415
CENTRO DE QUIMICA INORGANICA "DR. PEDRO J. AYMONINO"
Unidad Ejecutora - UE
artículos
Título:
Stannathianes as activated polythiols for the synthesis of functionalized macrocyclic polythiolactones
Autor/es:
ERBEN, MAURICIO FEDERICO; DELGADO ESPINOSA, ZULY YULIANA
Revista:
TETRAHEDRON LETTERS
Editorial:
PERGAMON-ELSEVIER SCIENCE LTD
Referencias:
Lugar: Amsterdam; Año: 2017 vol. 58 p. 1484 - 1486
ISSN:
0040-4039
Resumen:
We synthesized novel macrocyclic dithiolactones bearing endocyclic ether, polyether and lactone groups using new stannadithianes as tin templates in the condensation reaction with acid dichlorides and demonstrated an extension of this method toward synthesizing spirotetrathiolactones of controlled size. The structures of all synthesized compounds were characterized by spectroscopic methods.