CENTRO DE QUIMICA INORGANICA "DR. PEDRO J. AYMONINO"
Unidad Ejecutora - UE
An experimental and theoretical study of the vibrational properties of CF3SO2Cl
L. E. FERNÁNDEZ; E. L. VARETTI
Journal of the Argentine Chemical Society
Año: 2009 vol. 97 p. 199 - 199
The infrared and Raman spectra of CF3SO2Cl were obtained and analyzed. An assignmentof the observed bands is proposed, based in a comparison with similar molecules and with atheoretical calculation of frequencies and normal modes of vibration made by means of densityfunctional theory (DFT) techniques. The original force field in Cartesian coordinates wastransformed to local symmetry coordinates and subsequently scaled to reproduce the experimental frequencies.