CEQUINOR 05415
CENTRO DE QUIMICA INORGANICA "DR. PEDRO J. AYMONINO"
Unidad Ejecutora - UE
artículos
Título:
O-alkyl N-methoxycarbonyl thiocarbamates, ROC(S)N(H)C(O)OCH3 (R = CH3, CH3CH2): Structural and Vibrational Properties in the Solid Phase
Autor/es:
TORRICO VALLEJOS, SONIA; ERBEN, MAURICIO FEDERICO; PIRO, OSCAR; CASTELLANO, E.E.; DELLA VÉDOVA, CARLOS OMAR
Revista:
POLYHEDRON
Editorial:
Elsevier
Referencias:
Año: 2009 vol. 28 p. 937 - 946
ISSN:
0277-5387
Resumen:
The synthesis and full characterization of two O-alkyl N-methoxycarbonyl thiocarbamates, ROC(S)N(H)C(O)OCH3 (R= CH3-, CH3CH2-), are reported. The structure and conformation are studied by using a combined experimental (X-ray, IR and Raman spectroscopy) and theoretical approach. The crystal structure of CH3CH2OC(S)N(H)C(O)OCH3 shows the presence of centro-symmetric dimeric units held by N−H···S=C hydrogen bonds. The conjugative (resonance) effect in the thiocabamate group -OC(S)N(H)- is discussed.
