CEQUINOR 05415
CENTRO DE QUIMICA INORGANICA "DR. PEDRO J. AYMONINO"
Unidad Ejecutora - UE
artículos
Título:
Vibrational Spectra of Three New Diarsenates Containing Scandium(III)
Autor/es:
ENRIQUE JOSE BARAN; K SCHWENDTNER; U KOLITSCH
Revista:
Journal of Raman Spectroscopy
Editorial:
J. Wiley & Sons, Ltd.
Referencias:
Lugar: Londres; Año: 2006 vol. 37 p. 1335 - 1340
Resumen:
The powder FTIR and Raman spectra of the new isotypic diarsenates RbScAs2O7, TlScAs2O7 and (NH4)ScAs2O7 are discussed with a factor group analysis, on the basis of their known structural characteristics. The spectroscopic behavior clearly reflects all the structural peculiarities and also confirms the rotational quenching of the NH4(+) cation in (NH4)ScAs2O7. The crystal structure of TlScAs2O7 is also reported for the first time and is briefly discussed.
