CEQUINOR   05415
CENTRO DE QUIMICA INORGANICA "DR. PEDRO J. AYMONINO"
Unidad Ejecutora - UE
artículos
Título:
Structural and Spectroscopic Characterization of Bis(thiosaccharinato)bis(benzimidazole)cadmium(II)
Autor/es:
TARULLI, S; QUINZANI, OV; PIRO, OE; CASTELLANO, EE; ENRIQUE JOSE BARAN
Revista:
Journal of Molecular Structure
Editorial:
Elsevier
Referencias:
Lugar: Amsterdam, Holanda; Año: 2006 vol. 797 p. 56 - 56
ISSN:
0022-2860
Resumen:
   The crystal structure of [Cd(tsac)2(bzim)2].CH3OH (tsac = anion of thiosaccharin; bzim = benzimidazole) has been determiend by single crystal X-ray diffractometry. It crystallizes in the triclinic spece group P(-1) with Z = 2. The Cd(II) cation is in a distorted tetrahedral environment coordinated to the S-atom of two thiosaccharinato anions and to the N-atom of two benzimidazole molecules. The FTIR spectrum of the complex is also recorded and briefly discussed. Some comparisons with related complexes are made.