CENTRO DE QUIMICA INORGANICA "DR. PEDRO J. AYMONINO"
Unidad Ejecutora - UE
X-Ray Diffraction and IR-Spectroscopic Characterization of AgLnTiO4 Oxides Related to the K2NiF4 Structural Type
LAVAT, AE; ENRIQUE JOSE BARAN
Journal of the Brazilian Chemical Society
Sociedade Brasileira de Quimica
Lugar: Sao Paulo, Brasil; Año: 2006 vol. 17 p. 1436 - 1436
Ternary oxides of the type AgLnTiO4 (with Ln = La, Nd, Sm, Eu, Gd, Dy, Y) have been prepared and their unit cell parameters determined by X-ray powder diffractometry. They are related to the K2NiF4 structural type, with the Ag(I) and Ln(III) cations distributed in an ordered way on the K-sublattice. The IR spectra of these materials were recorded and discussed on the basis of their structural peculiarities and by comparison with those of related oxides. They show a close relationship with the parent NaLnTiO4 materials.