CEQUINOR 05415
CENTRO DE QUIMICA INORGANICA "DR. PEDRO J. AYMONINO"
Unidad Ejecutora - UE
artículos
Título:
Pd(thiosaccharinato)2.H2O, the First Thiosaccharinato Complex of a Platinum-Group Metal
Autor/es:
M VIEITES; GAMBINO, D; M GONZALEZ; H.CERECETTO; TARULLI, S; QUINZANI, OV; ENRIQUE JOSE BARAN
Revista:
Journal of Coordination Chemistry
Editorial:
Taylor & Francis
Referencias:
Lugar: Londres; Año: 2006 vol. 59 p. 101 - 106
ISSN:
0095-8972
Resumen:
A Pd(II) complex of the thiosaccharinato (tsac) anion, of stoichiometry Pd(tsac)2.H2O, was prepared by interaction of Na2PdCl4 with thiosaccharin in methanol and characterized by IR and 1H and 13C NMR spectroscopy. These spectral studies confirmed interaction of the metal center with the thiosaccharin acting as a bidentate ligand through thiol group and N-atom. NMR measurements also confirmed that in solution thiosaccharin is mainly present in its thiolate tautomeric form.
