CEQUINOR   05415
CENTRO DE QUIMICA INORGANICA "DR. PEDRO J. AYMONINO"
Unidad Ejecutora - UE
artículos
Título:
Crystal structure and vibrational spectra of [Ru(NH3)4(OH)(NO)]?ZnCl4
Autor/es:
M. E. CHACÓN VILLALBA; G. ECHEVERRÍA; P.J. AYMONINO ; E. L. VARETTI
Revista:
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
Editorial:
SPRINGER/PLENUM PUBLISHERS
Referencias:
Lugar: New York ; Año: 2011 vol. 41 p. 508 - 508
ISSN:
1074-1542
Resumen:
The crystal structure of [Ru(NH3)4(OH)(NO)] ZnCl4 was determined by X-ray diffraction methods. Such study confirmed the already reported data for the complex cation and allowed a description of the main features of the lattice structure. An infrared and Raman study of that compound was also performed in order to revise the existing assignment of the vibrational bands. This last study, backed by quantum chemical calculations, lead to a reinterpretation of the spectra. Data were also collected on the structural and vibrational  characteristics of the ZnCl4 2- anion.3)4(OH)(NO)] ZnCl4 was determined by X-ray diffraction methods. Such study confirmed the already reported data for the complex cation and allowed a description of the main features of the lattice structure. An infrared and Raman study of that compound was also performed in order to revise the existing assignment of the vibrational bands. This last study, backed by quantum chemical calculations, lead to a reinterpretation of the spectra. Data were also collected on the structural and vibrational  characteristics of the ZnCl4 2- anion.
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