IQUIR   05412
INSTITUTO DE QUIMICA ROSARIO
Unidad Ejecutora - UE
congresos y reuniones científicas
Título:
Studies on biomimetic singlet oxygen oxidations: application to the synthesis of Zanthoxylum quinoline alkaloids
Autor/es:
MIRTA MISCHNE; MARTIN J. RIVEIRA
Lugar:
Budapest
Reunión:
Simposio; 18TH TETRAHEDRON SYMPOSIUM; 2017
Institución organizadora:
Editorial Elsevier
Resumen:
Simulenoline (1) is a biologically active alkaloidthat, along with related peroxysimulenoline (2), has been isolated from the roots of Formosan Zanthoxylum simulans, a flowering shrubfrom which Sichuan pepper is produced (Scheme 1).1 It caninstinctively be proposed that both 1and 2 may originate from naturalpyran 3 via a singlet oxygen (1O2)ene-type reaction