IQUIR 05412
INSTITUTO DE QUIMICA ROSARIO
Unidad Ejecutora - UE
congresos y reuniones científicas
Título:
New DiMn Catalysts for Water-Oxidation in Homogeneous Medium
Autor/es:
SOLÍS, V.; BERNATENE, E.; PALOPOLI, C.; SIGNORELLA, S.
Lugar:
Chascomús
Reunión:
Congreso; Latin American Meeting on Biological Inorganic chemistry ? IV LABIC and V WOQUIBIO; 2014
Institución organizadora:
INQUIMAE
Resumen:
In this work we employ ligands rich in O-donor sites with a central phenolato and terminal bis-carboxylato or phenolato/carboxylato groups. These ligands were chosen because phenols afford Mn complexes stable in aqueous media while carboxylato groups are able to act as intramolecular bases to assist the proton transfer coupled to water oxidation.
