IQUIR 05412
INSTITUTO DE QUIMICA ROSARIO
Unidad Ejecutora - UE
artículos
Título:
Rewiring Chemical Networks Based on Dynamic Dithioacetal and Disulfide Bonds
Autor/es:
LA-VENIA, AGUSTINA; ESCALANTE, ANDREA M.; ESCALANTE, ANDREA M.; FURLAN, RICARDO L. E.; ORRILLO, A. GASTÓN; FURLAN, RICARDO L. E.; ORRILLO, A. GASTÓN; LA-VENIA, AGUSTINA
Revista:
CHEMISTRY-A EUROPEAN JOURNAL
Editorial:
WILEY-V C H VERLAG GMBH
Referencias:
Lugar: Weinheim; Año: 2018 vol. 24 p. 3141 - 3146
ISSN:
0947-6539
Resumen:
The control of the connectivity between nodes of synthetic networks is still largely unexplored. To address this point we take advantage of a simple dynamic chemical system with two exchange levels that are mutually connected and can be activated simultaneously or sequentially. Dithioacetals and disulfides can be exchanged simultaneously under UV light in the presence of a sensitizer. Crossover reactions between both exchange processes produce a fully connected chemical network. On the other hand, the use of acid, base or UV light connects different nodes allowing network rewiring.
