IQUIR 05412
INSTITUTO DE QUIMICA ROSARIO
Unidad Ejecutora - UE
artículos
Título:
A combined RCM-Bischler Napieralski strategy towards the synthesis of the carbon skeleton of excentricine and related stephaoxocanes
Autor/es:
LARGHI, E. L.; KAUFMAN, T. S.
Revista:
TETRAHEDRON
Editorial:
Elsevier
Referencias:
Año: 2008 vol. 64 p. 9921 - 9927
ISSN:
0040-4020
Resumen:
A convenient synthetic approach to a cyclodeca[ij] isoquinoline derivative, which embodies the carbon skeleton of excentricine and related stephaoxocanes, is described. The synthesis involves the combined use of ring closing metathesis and Bischler-Napieralski cyclizations for the construction of the homocyclic and nitrogen bearing rings, respectively.
