IQUIR 05412
INSTITUTO DE QUIMICA ROSARIO
Unidad Ejecutora - UE
artículos
Título:
Simple method for high purity Acylated Steryl Glucosides synthesis
Autor/es:
SEBASTIÁN N. JÄGER; MARTIN MITTELBACH; RODOLFO A.CABRERA; GUILLERMO R. LABADIE
Revista:
EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY
Editorial:
WILEY-V C H VERLAG GMBH
Referencias:
Lugar: Weinheim; Año: 2015 vol. 118 p. 827 - 833
ISSN:
1438-7697
Resumen:
The present work covers an important gap in the field of analytic standards synthesis of the plants minor component, the acyl steryl glucosides (ASG). A simple and powerful procedure that allows the synthesis of different ASG has been introduced. The regioselective acylation of steryl glucosides on the C-6-OH of the glucose was produced using sym-chollidine and acyl chloride. The reaction was optimized analyzing the conditions to maximize the isolated yield of the mono acylated product.
