IQUIR 05412
INSTITUTO DE QUIMICA ROSARIO
Unidad Ejecutora - UE
artículos
Título:
Alternate and Step-Economic Synthesis of the beta-Methylstyrene Chelating Pre-ligand of the Hoveyda-Grubbs II Catalyst
Autor/es:
SEBASTIÁN O. SIMONETTI; ENRIQUE L. LARGHI; TEODORO S. KAUFMAN
Revista:
ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL
Editorial:
ROUTLEDGE JOURNALS, TAYLOR & FRANCIS LTD
Referencias:
Lugar: Londres; Año: 2015 vol. 47 p. 227 - 231
ISSN:
0030-4948
Resumen:
The Hoveyda-Grubbs (HG)1 series of olefin metathesis catalysts are more selective, recyclable, and heat, air and moisture stable than their predecessors. We have recently reported an efficient one-pot sequential homo-bimetallic catalytic propenylation of haloarenes. As a further application of this novel strategy, with impact in fine chemistry, herein we report an alternate and convenient, step economic synthesis of 3, from commercial 2-halophenols 8a,b
