IQUIR 05412
INSTITUTO DE QUIMICA ROSARIO
Unidad Ejecutora - UE
artículos
Título:
Total Synthesis and Structural Elucidation of Cryptolatifolione
Autor/es:
NOVAES, L.F.T.; SAROTTI, A.M.; PILLI, R.A.
Revista:
RSC Advances
Editorial:
Royal Society of Chemistry
Referencias:
Año: 2015 p. 53471 - 53476
ISSN:
2046-2069
Resumen:
An enantioselective total synthesis of Cryptolatifolione and its C-8 epimer is presented in a protecting-group-free fashion. The synthesis relied on the use of a catalytic double Krische allylation, catalytic olefin metathesis and a C-H oxidation. Comparison of spectroscopical data of the synthetic isomers and natural product made possible the unequivocally elucidation of the absolute configuration of Cryptolatifolione.
