IQUIR 05412
INSTITUTO DE QUIMICA ROSARIO
Unidad Ejecutora - UE
artículos
Título:
Exploring structural effects of levoglucosenone derived chiral auxiliaries in asymmetric Diels-Alder cycloadditions
Autor/es:
ARIEL M. SAROTTI, ROLANDO A. SPANEVELLO, CARINE DUHAYON, JEAN-PIERRE TUCHAGUES AND ALEJANDRA G. SUÁREZ,
Revista:
TETRAHEDRON
Editorial:
Elsevier
Referencias:
Año: 2007 vol. 63 p. 241 - 251
ISSN:
0040-4020
Resumen:
New chiral auxiliaries derived from levoglucosenone were developed in a simple and efficient way and evaluated as chiral inductors in asymmetric Diels-Alder reactions between the corresponding acrylate derivatives and cyclopentadiene. The results showed an important influence between the absolute configuration of the C(2) center of the auxiliary and the level of stereoinduction obtained.
