IQUIR   05412
INSTITUTO DE QUIMICA ROSARIO
Unidad Ejecutora - UE
artículos
Título:
New chiral 1,2-aminoalcohols derived from biomass and their application in enantioselective diethyl zinc additions
Autor/es:
MARIA M ZANARDI; MARIA C. BOTTA; ALEJANDRA G. SUÁREZ
Revista:
TETRAHEDRON LETTERS
Editorial:
PERGAMON-ELSEVIER SCIENCE LTD
Referencias:
Lugar: Amsterdam; Año: 2014 vol. 55 p. 5832 - 5835
ISSN:
0040-4039
Resumen:
A convenient procedure for the preparation of chiral 1,2-aminoalcohols starting from levoglucosenone, a biomass derivative, is described. The 1,2-aminoalcohols, bearing primary, secondary, and tertiary amino groups, were tested as chiral catalysts in the asymmetric addition of diethyl zinc to benzaldehyde.