IQUIR 05412
INSTITUTO DE QUIMICA ROSARIO
Unidad Ejecutora - UE
artículos
Título:
Palladium-Catalyzed Cross-Coupling Reactions of Arylsiloxanes with Aryl Halides: Application to Solid-Supported Organic Synthesis
Autor/es:
TRAFICANTE, C. I.; DELPICCOLO, C. M. L.; MATA, E. G.
Revista:
ACS Combinatorial Science
Editorial:
American Chemical Society
Referencias:
Año: 2014 p. 211 - 214
ISSN:
2156-8952
Resumen:
The solid-phase version of the Pd-catalyzed Hiyama reaction between a variety of aryltriethoxysilanes and immobilized aryl halides was developed. Smooth crosscoupling was achieved to afford the corresponding biaryl products in moderate to excellent yields. The described protocol would be particularly useful for the construction of 4′-substituted 1,1′-biphenyl derivatives.
