IQUIR 05412
INSTITUTO DE QUIMICA ROSARIO
Unidad Ejecutora - UE
artículos
Título:
Synthesis of Tri-O-acetyl-D-allal from Levoglucosenone
Autor/es:
GIORDANO, E. D. V.; FRINCHABOY, A.; SUÁREZ, A. G.; SPANEVELLO, R. A.
Revista:
ORGANIC LETTERS
Editorial:
AMER CHEMICAL SOC
Referencias:
Lugar: Washington; Año: 2012 vol. 14 p. 4602 - 4605
ISSN:
1523-7060
Resumen:
Tri-O-acetyl-D-allal has been enantiospecifically synthesized in six steps from levoglucosenone in 55% overall yield. A key step in the synthesis is the anhydro bridge ring-opening with concomitant formation of a 1,3-oxathiolane-2-thione ring.
