IQUIR 05412
INSTITUTO DE QUIMICA ROSARIO
Unidad Ejecutora - UE
artículos
Título:
Microwave-assisted asymmetric Diels-Alder reaction using chiral auxiliaries derived from biomass
Autor/es:
SAROTTI, A. M.; SPANEVELLO, R. A.; SUÁREZ, A. G.
Revista:
ARKIVOC - ONLINE JOURNAL OF ORGANIC CHEMISTRY
Editorial:
ARKAT USA INC
Referencias:
Lugar: Florida; Año: 2011 vol. 2011 p. 31 - 37
ISSN:
1551-7004
Resumen:
Microwave-assisted asymmetric Diels-Alder reactions using levoglucosenone-derived chiral auxiliaries have been investigated. The cycloaddition reaction between the corresponding chiral acrylate and cyclopentadiene showed important rate enhancements under microwave irradiation compared to conventional heating conditions, whereas the yields and diastereoselectivities were not significantly affected.
