IQUIR 05412
INSTITUTO DE QUIMICA ROSARIO
Unidad Ejecutora - UE
artículos
Título:
The non-metathetic role of Grubbs? carbene complexes: from hydrogen-free reduction of á,â?unsaturated alkenes to solid-supported sequential cross-metathesis/reduction
Autor/es:
POEYLAUT-PALENA, A.A.; TESTERO, S. A.; MATA, E.G.
Revista:
CHEMICAL COMMUNICATIONS
Editorial:
ROYAL SOC CHEMISTRY
Referencias:
Año: 2011 vol. 47 p. 1565 - 1567
ISSN:
1359-7345
Resumen:
An efficient and high-yielding ??hydrogen-free?? reduction of a,b-unsaturated alkenes was carried out employing Grubbs? catalyst in a non-metathetic role and Et3SiH. Conditions were optimized under microwave irradiation. Application to the solid-phase organic synthesis allows a facile construction of sp3?sp3 carbon bonds through a sequential cross metathesis/olefin reduction.
