IQUIR 05412
INSTITUTO DE QUIMICA ROSARIO
Unidad Ejecutora - UE
artículos
Título:
Solid-phase cross metathesis: The effect of the non-immobilized olefin and the precatalyst on the intrasite interference
Autor/es:
POEYLAUT-PALENA, A.A.; MATA, E. G.
Revista:
Arkivoc
Editorial:
Arkat USA Inc.
Referencias:
Lugar: Zúrich, Suiza; Año: 2010 vol. iii p. 216 - 227
ISSN:
1424-6376
Resumen:
We have developed a study on the factors that influence the intrasite interactions in the cross metathesis on solid support. When such interactions are possible, the outcome of the intrasite by-product depends on the non-immobilized olefin and the precatalyst used. The comparatively poor reactivity of first generation Grubbs precatalyst makes the easier intrasite coupling to succeed.
