INTEC 05402
INSTITUTO DE DESARROLLO TECNOLOGICO PARA LA INDUSTRIA QUIMICA
Unidad Ejecutora - UE
artículos
Título:
Radical Amination with Trimethylstannylated Benzophenone Imine
Autor/es:
MARIE-CÉLINE LAMAS, SANTIAGO E. VAILLARD, BIRGIT WIBBELING AND ARMIDO STUDER
Revista:
ORGANIC LETTERS
Editorial:
AMER CHEMICAL SOC
Referencias:
Año: 2010 vol. 12 p. 2072 - 2075
ISSN:
1523-7060
Resumen:
Intermolecular radical amination reactions of various primary, secondary, and tertiary alkyl radicals by using trimethylstannylated benzophenone imine A as a novel radical acceptor to provide imines of type B are described. These imines are readily reduced with NaBH4 to the corresponding secondary amines C. The novel radical amination can be combined with typical radical cyclization reactions.
