The role of solvent in heterogeneous catalysis: A compressive approach for hydrogenation reactions

CARLOS R. APESTEGUÍA; NICOLÁS M. BERTERO; ANDRÉS F. TRASARTI; ALBERTO J. MARCHI

Munich

Congreso; 15th International Congress on Catalysis; 2012

IACS Council - German Catalysis Society

IntroductionThe synthesis of fine chemicals over solid catalysts often involves the use of solvents that may strongly influence the catalyst performance. Thus, the choice of suitable solvents is frequently critical to obtain high catalytic activity and selectivity. However, the optimal solvent selection requires a detailed knowledge on the relationship between the chemical nature of the solvents and the interactions taking place in the gas-liquid-solid catalytic systems. One of the most common types of catalytic reactions carried out in the presence of solvents is the hydrogenation of organic compounds. In particular, the selective hydrogenation of aromatic ketones into the corresponding alcohols on metal-based catalysts in the presence of different solvents has been widely studied. Here, the solvent effect on catalyst activity and selectivity for the liquid-phase hydrogenation of acetophenone (AP) to 1-phenylethanol was thoroughly investigated over Ni/SiO2. Solvents of different properties and polarities were used: i) protic solvents: methanol (MeOH), ethanol (EtOH), 1-propanol (1-PrOH) and 2-propanol (2-PrOH); ii) aprotic polar solvents: acetonitrile (ACN), γ-butyrolactone (GBL) and tetrahydrofuran (THF); iii) aprotic apolar solvents: cyclohexane (CHX), toluene (TOL) and benzene (BZN). The relative interactions solvent?catalyst, solvent?reactant and reactant?catalyst and their influence on the activity pattern were considered in the analysis. Concerning the influence of the solvent-reactant interaction, classical polarity parameters (e.g. dipole moment μ and dielectric constant ε) and other solvatochromic scales (e.g. hydrogen-bond donor (α) and hydrogen-bond acceptor (β) parameters, π∗ polarity/polarizability index, Kosower?s Z and ET(30) scales) were taken into account . The influence of H2 solubility in the solvents was also considered. For the solvent-catalyst and reactant-catalyst interactions, the corresponding molar adsorption enthalpies were measured calorimetrically and compared.