INCAPE   05401
INSTITUTO DE INVESTIGACIONES EN CATALISIS Y PETROQUIMICA "ING. JOSE MIGUEL PARERA"
Unidad Ejecutora - UE
artículos
Título:
Microreactor with silver-loaded metal-organic framework films for gas-phase reactions
Autor/es:
JOSE LUIS FERNÁNDEZ; R. PAPPURELLO; JUAN M. ZAMARO; EDUARDO E. MIRÓ
Revista:
CHEMICAL ENGINEERING JOURNAL
Editorial:
ELSEVIER SCIENCE SA
Referencias:
Lugar: Amsterdam; Año: 2016 vol. 313 p. 1468 - 1476
ISSN:
1385-8947
Resumen:
Microreactors of copper foils with microchannels having zeolitic imidazolate framework-8 (ZIF-8) films were developed. The films were obtained by direct solvothermal synthesis on the microchannels; theypresented micrometric thicknesses and homogeneity, and were activated with highly dispersed silver species. The MOF-based microreactors showed high activity and stability in the carbon monoxide oxidation, which is a benchmark for exothermic gas-phase reactions. The results could bring new perspectivesin the development of microreactors for heterogeneous catalytic gas-phase reactions based on other MOF films as supports of active phases.