Behavior of PtPb/MgAl2O4catalysts with different Pb contents andand trimetallic PtPbIn catalysts in n-butane dehydrogenation

DRA. SONIA BOCANEGRA; ING. OSVALDO SCELZA; DR. SERGIO DE MIGUEL

APPLIED CATALYSIS A-GENERAL

ELSEVIER SCIENCE BV

Lugar: Amsterdam; Año: 2013 vol. 468 p. 135 - 142

0926-860X

The behavior of PtPb/MgAl2O4catalysts in butenes production through the n-butane dehydrogenation has shown that at low contents, the Pb acts as promoter, improving the conversion and selectivity, whereas at higher contents it has a poisoning effect on the catalytic activity. The PtPb(0.25 wt%)/MgAl2O4catalystshowed the maximum yield to butenes. The characterization results of PtPb catalysts displayed that at low Pb contents there are both dilution and electronic effects of Pb on the Pt sites. On the other hand, athigh Pb contents, there is a strong blocking effect of the Pb on the active sites of Pt. In order to study the effect of the In addition in different sequences to PtPb(0.25 wt%)/MgAl2O4catalyst, two catalysts were prepared: PtPb(0.25%)In(0.28 wt%)/MgAl2O4 and PtIn(0.28%)Pb(0.25 wt%)/MgAl2O4. The first catalyst did not show significant advantages with respect to the catalytic behavior of the PtPb(0.25 wt%)/MgAl2O4,but the second trimetallic catalyst displayed an increase of both the conversion and the selectivity. The characterization results indicated similar effects of blocking and dilution of promoters on the active sites of Pt for both trimetallic catalysts, but the best catalyst, PtIn(0.28%)Pb(0.25 wt%)/MgAl2O4, showed the highest percentages of In0 and Pb0, thus indicating stronger interaction between Pt, Pb and In.