INCAPE   05401
INSTITUTO DE INVESTIGACIONES EN CATALISIS Y PETROQUIMICA "ING. JOSE MIGUEL PARERA"
Unidad Ejecutora - UE
artículos
Título:
Gas-Phase Maleic Anhydride Hydrogenation Over Ni/SiO2?Al2O3 Catalysts: Effect of Metal Loading
Autor/es:
C.I.MEYER; S.A.REGENHARDT; M.E:BERTONE; A.J.MARCHI; T.F. GARETTO
Revista:
CATALYSIS LETTERS
Editorial:
SPRINGER
Referencias:
Lugar: Berlin; Año: 2013 vol. 143 p. 1067 - 1073
ISSN:
1011-372X
Resumen:
The gas-phase maleic anhydride hydrogenation was studied at 170 C and 1 bar using Ni/SiO2?Al2O3 catalysts varying metal loading. The maximum c-butyrolactoneselectivity was reached for a 10 wt% nickel load. On the basis of temperature programmed experiments, it is proposed that new active sites in selective succinic anhydridehydrogenolysis are formed when Ni loads are higher than 8 wt%.