INCAPE   05401
INSTITUTO DE INVESTIGACIONES EN CATALISIS Y PETROQUIMICA "ING. JOSE MIGUEL PARERA"
Unidad Ejecutora - UE
artículos
Título:
Efficiency of ethanol conversion induced by controlled modification of pore structure and acidic properties of alumina catalysts
Autor/es:
LEANDRO MARTINS; DILSON CARDOSO; PETER HAMER; TERESITA GARETTO; SANDRA H PULCINELLI; CELSO V. SANTILLI
Revista:
APPLIED CATALYSIS A-GENERAL
Editorial:
ELSEVIER SCIENCE BV
Referencias:
Año: 2011 vol. 398 p. 59 - 65
ISSN:
0926-860X
Resumen:
Bimodal porous alumina catalysts with both continuous macropores and mesopores were prepared using a dual soft template method. The addition of decahydronaphthalene as emulsifier agent successfully contributed to the formation of macropores. The effectiveness of macropore insertion was evaluated in the model reaction of ethanol dehydration at 300 ◦C. Judging from the results obtained by acidity measurements using temperature programmed desorption of ammonia and the performance of these catalysts in the ethanol dehydration, the introduction of macropores in the catalyst structure enhanced the ethanol conversion