CIDCA   05380
CENTRO DE INVESTIGACION Y DESARROLLO EN CRIOTECNOLOGIA DE ALIMENTOS
Unidad Ejecutora - UE
capítulos de libros
Título:
Light Induced Reactions in Cryogenic Matrices
Autor/es:
RUI FAUSTO Y ANDREA GÓMEZ-ZAVAGLIA
Libro:
Photochemistry (volumen 37)
Editorial:
Royal Society of Chemistry
Referencias:
Lugar: Londres; Año: 2009; p. 72 - 99
Resumen:
This chapter deals with light induced reactions in cryogenic matrices. Photochemical reactions induced by UV/visible irradiation of matrix isolated organic compounds, ranging from conformational isomerizations to complex bond-breaking/bond-forming processes, will be addressed. The effects of the media on the chemical processes, including direct participation of the matrix noble gas as a reactant to form novel covalently bound noble gas containing molecules, will also be discussed. Finally, (N)IR induced reactions in cryomatrices will be considered, as well as intramolecular vibrational energy relaxation/redistribution processes involved in these reactions.