Zircon?zirconia (ZrSiO4?ZrO2) dense ceramic composites by spark plasma

NICOLAS M. RENDTORFF , SALVATORE GRASSO C, CHUNFENG HUC,D, GUSTAVO SUAREZ ,AGLIETTI ESTEBAN

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY

ELSEVIER SCI LTD

Lugar: Amsterdam; Año: 2012 vol. 32 p. 787 - 793

0955-2219

Abstract Dense reinforced zircon (ZrSiO4)?20 vol.% zirconia (ZrO2) ceramic composites were obtained by spark plasma sintering (SPS) starting from high energy milled commercially available powders. The sintering temperature and holding time resulted in two different microstructural configurations. In the first configuration, the nano sized zirconia nanoparticles (100 nm) act as a bonding phase continuously dispersed along the zircon micronic (1?4m) grains. In the second one, a continuous zircon phase with well dispersed zirconia grains was achieved. Both configurations led to improvement in fracture toughness and Vickers hardness if compared to pure zircon material processed under the same sintering condition. By comparing the developed microstructure configurations, the second one exhibits higher fracture toughness (almost 4.0MPam1/2) due to the more effective zirconia reinforcement effects. © 2011 Elsevier Ltd. All rights reserved. © 2011 Elsevier Ltd. All rights reserved. energy milled commercially available powders. The sintering temperature and holding time resulted in two different microstructural configurations. In the first configuration, the nano sized zirconia nanoparticles (100 nm) act as a bonding phase continuously dispersed along the zircon micronic (1?4m) grains. In the second one, a continuous zircon phase with well dispersed zirconia grains was achieved. Both configurations led to improvement in fracture toughness and Vickers hardness if compared to pure zircon material processed under the same sintering condition. By comparing the developed microstructure configurations, the second one exhibits higher fracture toughness (almost 4.0MPam1/2) due to the more effective zirconia reinforcement effects. © 2011 Elsevier Ltd. All rights reserved. © 2011 Elsevier Ltd. All rights reserved. 4)?20 vol.% zirconia (ZrO2) ceramic composites were obtained by spark plasma sintering (SPS) starting from high energy milled commercially available powders. The sintering temperature and holding time resulted in two different microstructural configurations. In the first configuration, the nano sized zirconia nanoparticles (100 nm) act as a bonding phase continuously dispersed along the zircon micronic (1?4m) grains. In the second one, a continuous zircon phase with well dispersed zirconia grains was achieved. Both configurations led to improvement in fracture toughness and Vickers hardness if compared to pure zircon material processed under the same sintering condition. By comparing the developed microstructure configurations, the second one exhibits higher fracture toughness (almost 4.0MPam1/2) due to the more effective zirconia reinforcement effects. © 2011 Elsevier Ltd. All rights reserved. © 2011 Elsevier Ltd. All rights reserved. 1/2) due to the more effective zirconia reinforcement effects. © 2011 Elsevier Ltd. All rights reserved. Keywords: Zircon; Zirconia; Composites; SinteringZircon; Zirconia; Composites; Sintering