Morphology and properties of neutralized chitosan-cellulose nanocrystals biocomposite films

PERUZZO PJ; SERRADELL MA; AMALVY JI; ANBINDER PS; CORSELLO FA; BOLLA PA; PERUZZO PJ; SERRADELL MA; AMALVY JI; ANBINDER PS; BOLLA PA; CORSELLO FA

CARBOHYDRATE POLYMERS

ELSEVIER SCI LTD

Lugar: Amsterdam; Año: 2017 vol. 156 p. 452 - 459

0144-8617

Chitosan/cellulose nanocrystals (CH-CN) films were obtained by casting of dispersions, and treated with NaOH for neutralization proposes. The composition of films was varied from 1 to 10 wt.% of CN. Changes in the morphology of thesystems were correlated with the different properties studied. FTIR revealed the presence of a weak interaction between the polymer matrix and nanofiller, confirmed by a slightly increase in thermal stability. SEM images suggested that incorporating CN amounts higher than 3 wt.% generates phase-segregated systems, and SAXS showed that CH avoid the typical organization of CN at concentrations below 5 wt.%. Improved performance against water was obtained in compositematerials comparing to the pure polymer matrix, as well as CH and CH-CN films did not show antibacterial activity demonstrating that remnant acetic acid, when no neutralization step is done, plays an important role in this property.