Carbon nanotubes and nanofibers synthesized by CVD on nickel coatings deposited with a vacuum arc

ESCOBAR, M.M.; GIULIANI, L.; CANDAL R.J.; LAMAS D.G.; CASO A.; RUBIOLO G.; GRONDONA, D.; GOYANES S.; MÁRQUEZ, A.

JOURNAL OF ALLOYS AND COMPOUNDS

ELSEVIER SCIENCE SA

Año: 2010 vol. 495 p. 446 - 449

0925-8388

Nanotubes and nanofibers were grown on Ni coatings deposited by plasma generated with a pulsed vacuum arc on silicon wafers using three different bias conditions: at floating potential (approximately +30V respect to the grounded cathode); at ground potential; and at −60 V. An atomic force microscopy study showed that the Ni film morphology was affected by the bias condition of the substrate. The morphology of carbonaceous species depended on Ni-films characteristics. FE-SEM and TEM analyses have shown that nanofibers growth was favoured on Ni coatings deposited at −60V whereas nanotubes grew mainly on Ni coatings obtained at floating and ground potentials. Hence, thisnewmethod to produce the precursor can be optimized to obtain nanotubes or nanofibers varying the substrate bias for the Ni deposition. grew mainly on Ni coatings obtained at floating and ground potentials. Hence, thisnewmethod to produce the precursor can be optimized to obtain nanotubes or nanofibers varying the substrate bias for the Ni deposition. study showed that the Ni film morphology was affected by the bias condition of the substrate. The morphology of carbonaceous species depended on Ni-films characteristics. FE-SEM and TEM analyses have shown that nanofibers growth was favoured on Ni coatings deposited at −60V whereas nanotubes grew mainly on Ni coatings obtained at floating and ground potentials. Hence, thisnewmethod to produce the precursor can be optimized to obtain nanotubes or nanofibers varying the substrate bias for the Ni deposition. grew mainly on Ni coatings obtained at floating and ground potentials. Hence, thisnewmethod to produce the precursor can be optimized to obtain nanotubes or nanofibers varying the substrate bias for the Ni deposition. −60 V. An atomic force microscopy study showed that the Ni film morphology was affected by the bias condition of the substrate. The morphology of carbonaceous species depended on Ni-films characteristics. FE-SEM and TEM analyses have shown that nanofibers growth was favoured on Ni coatings deposited at −60V whereas nanotubes grew mainly on Ni coatings obtained at floating and ground potentials. Hence, thisnewmethod to produce the precursor can be optimized to obtain nanotubes or nanofibers varying the substrate bias for the Ni deposition. grew mainly on Ni coatings obtained at floating and ground potentials. Hence, thisnewmethod to produce the precursor can be optimized to obtain nanotubes or nanofibers varying the substrate bias for the Ni deposition. −60V whereas nanotubes grew mainly on Ni coatings obtained at floating and ground potentials. Hence, thisnewmethod to produce the precursor can be optimized to obtain nanotubes or nanofibers varying the substrate bias for the Ni deposition.